Most professional tie-dyers use thickener with their dyes. This especially applies to the dyers that mass produce tie-dye for wholesale and silkscreening. The thickener primarily keeps the dyes from spreading too fast, and it prevents them from blending much with the adjoining colors, but it also stops the separation or bleeding.
In fact, one way I can easily spot a "store-bought" shirt is by looking at how much bleeding or blending the shirt has. If there isn't any, it's probably store-bought. The other thing I look for is the density of color. Store-bought shirts usually have very little or no white on them--it's all perfectly colored.
It's useful to create a color sampler with the colors of dye you're using (as Dharma says, "test, test, TEST!"). If you do it without thickener, you can get an idea of what separates and what doesn't. Here on my test T-shirt (T-shirts are cheap!), I found that a mixture of fuchsia and lemon yellow gave a great yellow halo, and chocolate brown bled bluish, for example.
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